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The digital collections of the Library of Congress contain a wide variety of primary source materials associated with James Madison, including manuscripts, government documents, printed ephemera, newspaper articles, and books. Provided below is a link to the home page for each relevant digital collection along with selected highlights.
James Madison Papers, 1723 to 1859
Alexander Hamilton Papers
George Washington Papers
Chronicling America
James Monroe Papers
Printed Ephemera: Three Centuries of Broadsides and Other Printed Ephemera
Rare Book Selections
Thomas Jefferson Papers, 1606 to 1827