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The digital collections of the Library of Congress contain a wide variety of primary source materials associated with James Monroe, including manuscripts, letters, government documents, printed ephemera, and newspaper articles. Provided below is a link to the home page for each relevant digital collection along with selected highlights.
James Monroe Papers
Documents from the Continental Congress and the Constitutional Convention, 1774-1789
George Washington Papers
Chronicling America
James Madison Papers, 1723 to 1859
Printed Ephemera: Three Centuries of Broadsides and Other Printed Ephemera
Thomas Jefferson Papers, 1606 to 1827